Feasibility of solar thermochemical natural gas desulphurization and hydrogen generation with a membrane reactor
نویسندگان
چکیده
Natural gas has enormous known reserves and is a relatively environment-friendly energy carrier compared to other fossil sources, but its utilization often limited by the presence of impurities such as H2S. The traditional desulphurization processes for natural have several disadvantages, high costs, significant process complexity expensive equipment maintenance requirements. In this study, thermochemical system containing an H2 permeable membrane reactor driven mid/low-temperature solar proposed analyzed. process, stored hydrogen energy, while simultaneously carbon from CH4 captured CS2. generated transported through reactor, which shifts equilibrium H2S methane reformation (H2SMR) reaction forward allows conversion at lower temperature thus cost collector. A thermodynamic analysis was conducted in range 300 °C 700 under permeate pressures 10−2 bar 10−5 1 with space velocity 2.7 h−1. CO2 emissions reduction achieved 115 kg m−2 annually, first-law efficiency solar-to-fuel maximums 72.4% 21.0%, respectively.
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ژورنال
عنوان ژورنال: Journal of Cleaner Production
سال: 2021
ISSN: ['0959-6526', '1879-1786']
DOI: https://doi.org/10.1016/j.jclepro.2021.127835