Feasibility of solar thermochemical natural gas desulphurization and hydrogen generation with a membrane reactor

نویسندگان

چکیده

Natural gas has enormous known reserves and is a relatively environment-friendly energy carrier compared to other fossil sources, but its utilization often limited by the presence of impurities such as H2S. The traditional desulphurization processes for natural have several disadvantages, high costs, significant process complexity expensive equipment maintenance requirements. In this study, thermochemical system containing an H2 permeable membrane reactor driven mid/low-temperature solar proposed analyzed. process, stored hydrogen energy, while simultaneously carbon from CH4 captured CS2. generated transported through reactor, which shifts equilibrium H2S methane reformation (H2SMR) reaction forward allows conversion at lower temperature thus cost collector. A thermodynamic analysis was conducted in range 300 °C 700 under permeate pressures 10−2 bar 10−5 1 with space velocity 2.7 h−1. CO2 emissions reduction achieved 115 kg m−2 annually, first-law efficiency solar-to-fuel maximums 72.4% 21.0%, respectively.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Thermochemical solar hydrogen generation.

Solar direct, indirect and hybrid thermochemical processes are presented for the generation of hydrogen and compared to alternate solar hydrogen processes. A hybrid solar thermal/electrochemical process combines efficient photovoltaics and concentrated excess sub-bandgap heat into highly efficient elevated temperature solar electrolysis of water and generation of H2 fuel utilizing the thermodyn...

متن کامل

Efficient production of hydrogen from natural gas steam reforming in palladium membrane reactor

Ultra-thin, high performance composite palladium membrane, developed via a novel electroless plating method, was applied to construct a membrane reactor for methane steam reforming reaction, which was investigated under the following working conditions: temperature 723–823 K, pressure 300–900 kPa, gas hourly space velocity (GHSV) 4000–8000 mL g 1 cat h , steam-to-carbon feed ratio (S/C, mol/mol...

متن کامل

Thermochemical hydrogen generation: heat requirements and costs.

We are pleased that Dagan et al. have found an earlier reference (1) than Reiss (2), whom we cited (3), on the production of alternating single impulses in a network of model neurons. The general properties of reciprocally inhibitory neuronal networks are discussed by Sherrington (4), who in turn cites a number of 19th-century examples of similar alternating behaviors, both experimental and the...

متن کامل

IV.A.11 Ceramic Membrane Reactor Systems for Converting Natural Gas to Hydrogen and Synthesis Gas (ITM Syngas)

• Research, develop and demonstrate the Ion Transport Membrane (ITM) Syngas ceramic membrane reactor system for the low-cost conversion of natural gas to hydrogen and synthesis gas. • Scale-up the ITM Syngas reactor technology through three levels of pilot-scale testing and precommercial demonstration. • Obtain the technical, engineering, operating and economic data necessary for the final step...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of Cleaner Production

سال: 2021

ISSN: ['0959-6526', '1879-1786']

DOI: https://doi.org/10.1016/j.jclepro.2021.127835